Recent results of Raman spectroscopy studies of lattice dynamics and phase transitions in ferroelectric thin films and superlattices are reviewed. Raman studies of SrTiO3, BaTiO3, and BaxSr1–xTiO3 thin films in comparison to corresponding single crystals are presented; essential differences in the lattice dynamics behavior of thin films and single crystals are discussed. Application of ultraviolet Raman spectroscopy for studies of nanoscale ferroelectric heterostructures, such as BaTiO3/SrTiO3 superlattices, is demonstrated.
This is an author-produced, peer-reviewed version of this article. The final, definitive version of this document can be found online at Journal of the American Ceramic Society, published by Blackwell Publishing. Copyright restrictions may apply. DOI: 10.1111/j.1551-2916.2008.02371.x
Tenne, Dmitri and Xi, Xiaoxing. (2008). "Raman Spectroscopy of Ferroelectric Thin Films and Superlattices". Journal of the American Ceramic Society, 91(6), 1820-1834. http://dx.doi.org/10.1111/j.1551-2916.2008.02371.x