Giant Magnetic-Field-Induced Strains in Polycrystalline Ni–Mn–Ga Foams
he magnetic shape-memory alloy Ni–Mn–Ga shows, in monocrystalline form, a reversible magnetic-field-induced strain (MFIS) up to 10%. This strain, which is produced by twin boundaries moving solely by internal stresses generated by magnetic anisotropy energy1, 2, 3, 4, can be used in actuators, sensors and energy-harvesting devices5, 6, 7. Compared with monocrystalline Ni–Mn–Ga, fine-grained Ni–Mn–Ga is much easier to process but shows near-zero MFIS because twin boundary motion is inhibited by constraints imposed by grain boundaries8, 9, 10. Recently, we showed that partial removal of these constraints, by introducing pores with sizes similar to grains, resulted in MFIS values of 0.12% in polycrystalline Ni–Mn–Ga foams11, close to those of the best commercial magnetostrictive materials. Here, we demonstrate that introducing pores smaller than the grain size further reduces constraints and markedly increases MFIS to 2.0–8.7%. These strains, which remain stable over >200,000 cycles, are much larger than those of any polycrystalline, active material.
Chmielus, Markus; Zhang, X. X.; Witherspoon, Cassie Lynne; Dunand, D. C.; and Müllner, Peter. (2009). "Giant Magnetic-Field-Induced Strains in Polycrystalline Ni–Mn–Ga Foams". Nature Materials, 8863-866. http://dx.doi.org/10.1038/NMAT2527