Nanohardness and Fracture Toughness of Combustion Chemical Vapor Deposition Deposited Yittria Stabilized Zirconia–Alumina Films
Composite films with compositions of 100% yttria stabilized zirconia (YSZ) and YSZ with 15, 30, 45, 62.8 (eutectic composition), 80 mol% alumina and 100% alumina films were deposited onto sapphire substrates using combustion chemical vapor deposition. Precursors of yttrium 2-ethylhexanoate, zirconium 2-ethylhexanoate and Al acetylacetonate dissolved in toluene at a total metal ion concentration of 0.002 M were used to produce films up to 1 μm thick. Flame temperatures at the substrate surfaces were 1550±50 °C and deposition rates fell between of 0.76–1.7 μm/h, depending on composition.
Nanohardness, determined with a Berkovich indenter, was constant at about 15 GPa for compositions less than 100% alumina. The 100% alumina films were about twice as hard as other films. The films' fracture toughness, determined with a cube corner indenter, increased with alumina content from 1.76±0.46 MPa m0.5 with no alumina to 2.49±0.32 MPa m0.5 at 30 mol% alumina. Further alumina increases had little effect on fracture toughness, with about 2.2 MPa m0.5 being the fracture toughness at 100% alumina.
Eutectic composition films, that were annealed for 2.5–10 h at 1500 °C, displayed coarsening of the second phase YSZ particles. Film hardness decreased by about half (∼22 to ∼11 GPa) after five or more hours of annealing, while fracture toughness reached a maximum of 3.33 MPa m0.5 after a 5 h anneal.
Stollberg, D. W.; Carter, W. B.; and Hampikian, Janet M.. (2005). "Nanohardness and Fracture Toughness of Combustion Chemical Vapor Deposition Deposited Yittria Stabilized Zirconia–Alumina Films". Thin Solid Films, 483(1-2), 211-217. http://dx.doi.org/10.1016/j.tsf.2005.01.002